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n2024-14_EN
with excellent stereochemical purity. During these studies, both diastereomers, ( S Si )- 3 und ( R Si )- 3 , were isolated in good yields and fully characterized. By employing single-crystal X-ray d [...] (SSi)- and (RSi)-Diastereomers of (1R,2S,5R)-Methyl(1-naphthyl)-phenylmenthoxysilane of Sommer J.-L. Kirchhoff, C. Strohmann, Z. anorg. allg. Chem. 2024 , 650 , e202400135. [...] approach may be attributed to interactions within the solid-state structures. Initial NMR studies confirmed the configurational stability of the menthoxysilanes under elevated reaction temperatures and basic …